vim /etc/rc.local

#!/bin/bash
# THIS FILE IS ADDED FOR COMPATIBILITY PURPOSES
#
# It is highly advisable to create own systemd services or udev rules
# to run scripts during boot instead of using this file.
#
# In contrast to previous versions due to parallel execution during boot
# this script will NOT be run after all other services.
#
# Please note that you must run 'chmod +x /etc/rc.d/rc.local' to ensure
# that this script will be executed during boot.

touch /var/lock/subsys/local

/usr/bin/vmhgfs-fuse .host:/ /mnt/win -o subtype=vmhgfs-fuse,allow_other   #示例

chmod +x /etc/rc.local

再次重启，就可以正常自动执行了。